Atom, Molecule, and Cluster Beams I: Basic Theory, by Hans Pauly

By Hans Pauly

This publication provides a constant, updated description of the super manifold and sundry experimental concepts which these days permit paintings with impartial debris. It lays the actual foundations of a few of the experimental strategies, which make the most of tools from such a lot fields in physics. accordingly this e-book is meant not just as a reference average for researchers, but additionally as a textbook to allow scholars to achieve an effective history and creation to the sector and its thoughts.

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Additional info for Atom, Molecule, and Cluster Beams I: Basic Theory, Production and Detection of Thermal Energy Beams

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Z is the partition function, which is a function of temperature and energy levels only, given by Z= Lgj exp(-eJkT). 3) j All thermodynamic quantities can be expressed in terms of the partition function Z. Therefore, if detailed information about the energy levels of the system is available, it is possible to calculate a11 thermodynamic properties from the partition function. e. 5) where R = kNo (No is Avogadro's number) is the molar gas constant. 1), the energy ei of the i-th state is well approximated to be additive and consisting of three contributions, the internal energy and the specific heat also constitute sums of three contributions.

5), which are studied intensively, since the limits of present day opticallithography are already recognizable while striving to reach structures of dimensions less than 100 nm. 4 Fast Beam Applications Fast molecular beams with energies between 10 and 100 keV are increasingly used in coaxiallaser spectroscopy [Neugart (1987), Müller et al. (1997)], in photofragment translation spectroscopy [Continetti et al. (1993)], and for precision determination oflifetimes [Tanner (1995), Warrington (1995)].

1989), Woenkhaus et al. (1996»). For more details and references see Chap. 4. Instead of measuring the deflection in an inhomogeneous electric field, recent work also uses the deflection of a beam upon passage through a standing light wave, detecting the deflection via the corresponding Doppler shift of the laser-induced fluorescence [Bonin and Kadar-Kallen (1993), Kadar-Kallen and Bonin (1994)]. Employing beams produced by laser ablation, hard-to-vaporize elements like uranium have also been made accessible.

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Atom, Molecule, and Cluster Beams I: Basic Theory, by Hans Pauly
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