By Paul T. Anastas, Carol A. Farris
content material: Benign by way of layout chemistry / Paul T. Anastas --
Environmentally benign chemical synthesis and processing for the financial system and the surroundings / Kenneth G. Hancock and Margaret A. Cavanaugh --
Microbial biocatalysis : synthesis of adipic acid from D-glucose / Karen M. Draths and John W. Frost --
Mechanistic examine of a catalytic method for carbonylation of nitroaromatic compounds : constructing possible choices to be used of phosgene / Wayne L. Gladfelter and Jerry D. Gargulak --
Preparative reactions utilizing seen gentle : excessive yields from pseudoelectrochemical transformation / Gary A. Epling and Qingxi Wang --
A photochemical replacement to the Friedel-Crafts response / George A. Kraus, Masayuki Kirihara, and Yusheng Wu --
Mn(III)-mediated electrochemical oxidative free-radical cyclizations / Barry B. Snider and Bridget A. McCarthy --
Supercritical carbon dioxide as a medium for undertaking free-radical reactions / James M. Tanko, Joseph F. Blackert, and Mitra Sadeghipour --
The collage of California-Los Angeles styrene technique / Orville L. Chapman --
new release of urethanes and isocyanates from amines and carbon dioxide / Dennis Riley, William D. McGhee, and Thomas Waldman --
Nucleophilic fragrant substitution for hydrogen : new halide-free routes for construction of fragrant amines / Michael okay. Stern --
Chemistry and catalysis : keys to environmentally more secure procedures / Leo E. Manzer --
replacement syntheses and different resource relief possibilities for premanufacture notification elements on the U.S. Environmental defense employer / Carol A. Farris, Harold E. Podall, and Paul T. Anastas --
Computer-assisted replacement artificial layout for pollutants prevention on the U.S. Environmental safeguard organisation / Paul T. Anastas, J. Dirk Nies, and Stephen C. DeVito.
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Pneumoniae and cat A from A. calcoaceticus. To ensure plasmid compatibility and plasmid maintenance, three vectors possessing compatible replication origins and each encoding resistance to a different antibiotic were identified. Vector pBR325 (53) contains the pMBl origin of replication. Insertion of the tkt, aroF, and aroB genes into pBR325 to produce pKD136 (43) results in a plasmid which confers resistance to ampicillin. Plasmid pSU19 (54), which confers resistance to chloramphenicol, contains the pl5A replication origin.
36. 37. Chairman; American Chemical Society: Division of Environmental Chemistry: Milwaukee, WI, 33(2); pp 328-329. Cusamano, J. CHEMTECH 1992, 22, pp 482-489. ), pp 44-45. S. Patent 5117063A, 1992, to Monsanto. K. J. Am. Chem. Soc. 1992, 114, pp 9237-9238. P. Organometallics 1992, 11, pp 900-907. 38. S. J. Org. Chem. 1993, 58(10), pp 2791-6. 39. T. 40. U. S. EPA. S. EPA: Cincinnati, OH, 1994, in press. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1994. Chapter 2 Environmentally Benign Chemical Synthesis and Processing for the Economy and the Environment 1 Kenneth G.
Twenty-five proposals were received and eight awards were made, providing about $1 million in research support. Two of the projects involved collaborations between chemists and engineers as well as between industry and academe, and were funded joindy by the two cooperating NSF Divisions. Among the funded projects were ones on oilwater interfacial synthesis as an alternative to traditional solvent-based routes; new methods for sulfolane synthesis, including computer-assisted synthetic design; zeolitebased catalysis in alkylation of isoparaffins with olefins; new methods for removing flux residues from printed wiring; production of crosslinked polymerfilmsthrough cationic photopolymerization; electrolytic steelmaking; and others.
