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1(a), (b). In (a), interstitial solid-solution, B atoms lodge between atoms of the host structure A. In (b), substitutional solid solution, the B atoms replace A atoms. In both, the B atoms may locally expand, contract, or distort the A structure but they do not upset it. The result is a crystal structure A with variable composition and lattice spacings. 1. (a) Interstitial solid solution and (b) substitutional solid solution. The A structure may be complex, like a zeolite silicate where whole water molecules can enter interstitially into tunnels between its atoms.
A) Mott, N. F. , Theory of the Properties of Metals and Alloys, Oxford, 1936. , The Modern Theory of Solids, McGraw-Hill, New York, 1940. , Superconductivity, Cambridge New York, 1960. (d) Lynton, E. , Superconductivity, Wiley, New York, 1962. (e) Reviews: Catterai, J. , Met. , 25, 11, 1966; Livington, J. D. and Schadler, H. , ' Prog. Mat. , 183,12, 1965. 3. , Dover, New York, 1953. (b) Smith, R. , Wave Mechanics of Crystalline Solids, Chapman and Hall, London, 1961. 4. (a) Pippard, A. ,Phil. Trans.
The direction cosines of K are lt = JC/K, m1 = y/K, 50 nx = z/K. 3) /2 = ft/N, m2 = kIN, n2 = 1/N, where N is V(A2 + /:2 + / 2 ). 3)
